Proper chemical storage is as important to safety as proper chemical handling. Often, seemingly logical storage ideas, such as placing chemicals in alphabetical order, may cause incompatible chemicals to be stored together.
Follow these guidelines for safe chemical storage:
In addition to the guidelines above, there are storage requirements for separating hazardous chemicals. Because an alphabetical storage system may place incompatible chemicals next to each other, group chemicals according to their hazard category (i.e., acids, bases, flammables, etc.).
Follow these guidelines to ensure that hazardous chemicals are stored safely:
The following table provides examples of incompatible chemicals:
| CHEMICAL | INCOMPATIBLE WITH . . . |
| Acetic acid | Chromic acid, nitric acid, hydroxyl compounds, ethylene glycol, perchloric acid, peroxides, permanganates |
| Acetylene | Chlorine, bromine, copper, fluorine, silver, mercury |
| Acetone | Concentrated nitric and sulfuric acid mixtures |
| Alkali metals | Water, carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens |
| Ammonia | Mercury, chlorine, calcium hypochlorite, iodine, bromine, hydrofluoric acid |
| Chlorates | Ammonium salts, acids, powdered metals, sulfur, finely divided organic or combustible materials |
| Chlorine | Ammonia, acetylene, butadiene, butane, methane, propane (or other petroleum gases), hydrogen, sodium carbide, benzene, finely divided metals, turpentine |
| Cyanide | Acids |
| Fluorine | Most other chemicals |
| Nitrates | Sulfuric acid |
| Oxygen | Oils, grease, hydrogen, flammable liquids, solids, or gases |
| Perchloric acid | Acetic anhydride, bismuth and its alloys, alcohol, paper, wood, grease, oils, |
| Sodium | Carbon tetrachloride, carbon dioxide, water |
| Sulfides | Acids |